Iridium plugs providing there the right heat range wont cause any problems,most racing plugs for 2 strokes are fine wire (NGK 105's,BREIX,EV,EGV etc).
Your not running excessive compression or squish (providing it is what you think) so there is no reason to mix AV with Super,if you want to raise the octane of the super you can use silkolene octane booster,but there really isnt any necessity.
if your worried about detonation or such it would make mores sense to jet the engine to the conditions/track type on the day,you cant jet for the circuit by a dyno run,all you can do is get a rough base line as to what gives good power.
Invest in a weather station,make notes and inspect the plug/piston to confirm the mixture is right not too make a decision based on what the plug says.
There's too many variables to guess what jetting to use,usually when it feels right it is right,the you confirm with a plug check,note the RAD/temp etc and then you can work from there.
Also bear in mind,its possible to get a high HP figure by leaning the jetting on a dyno run,this maybe ok on a twisty slow circuit but 10mins round snetterton and it will lose power and eventually grenade itself.
Reason being,fuel is used to cool the piston,so a fast rider/fast track needs more fuel than a novice/twisty track.
A richer than ideal mixture will give a slightly lower initial reading but it wont suffer from power fade after a few laps like a "on the edge" setting.
The slight swirling on the crown is something to do with the ignition on the KR (which is designed for unleaded which is fast burning) being not suited to the slow burn rate of the leaded fuel.
GP 125's and 250's (TZ and RS) run a night and day difference in settings between leaded and unleaded,
Ignition advance curve,
Squish and combustion chamber design,compression ratio.
Even the exhausts are different.
Jetting is changed etc etc.
Take that into account and the only reason for running leaded in an unleaded set up is in the belief that its safer (stops det),it may in theory but a too lean/advanced setup will still go bang whatever fuel you use.
Your right about the motul being different,it is,the off road stuff has anti fouling additives and a lower SAE,it still works well on a roadbike just not suited to constant high loading.
While there's nothing wrong with 800 road race,a castor/synthetic mix will give added protection against seizure and parts last longer.
Elf HTX and 747 are what most GP 125/250 guys use.
HTH a bit
ATB